Saturday, 20 March, 1965, 20:00
Naples, Italy
| 1 | Netherlands | Conny Van den bos | Het Is Genoeg | 5 points | 11th |
| 2 | United Kingdom | Kathy Kirby | I Belong | 26 points | 2nd |
| 3 | Spain | Conchita Bautista | Qué Bueno, Qué Bueno | — | 15th |
| 4 | Ireland | Butch Moore | I’m Walking The Streets In The Rain | 11 points | 6th |
| 5 | Germany | Ulla Wiesner | Paradies, Wo Bist Du? | — | 15th |
| 6 | Austria | Udo Jürgens | Sag Ihr, Ich Lass’ Sie Grüßen | 16 points | 4th |
| 7 | Norway | Kirsti Sparboe | Karusell | 1 points | 13th |
| 8 | Belgium | Lize Marke | Als Het Weer Lente Is | — | 15th |
| 9 | Monaco | Marjorie Noël | Va Dire à L’amour | 7 points | 9th |
| 10 | Sweden | Ingvar Wixell | Absent Friend | 6 points | 10th |
| 11 | France | Guy Mardel | N’avoue Jamais | 22 points | 3rd |
| 12 | Portugal | Simone de Oliviera | Sol De Inverno | 1 points | 13th |
| 13 | Italy | Bobby Solo | Se Piangi, Se Ridi | 15 points | 5th |
| 14 | Denmark | Birgit Brüel | For Din Skyld | 10 points | 7th |
| 15 | Luxembourg | France Gall | Poupée De Cire, Poupée De Son | 32 points | 1st |
| 16 | Finland | Viktor Klimenko | Aurinko Laskee Länteen | — | 15th |
| 17 | Yugoslavia | Vice Vukov | Ceznja | 2 points | 12th |
| 18 | Switzerland | Yovanna | Non à Jamais Sans Toi | 8 points | 8th |